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This is not completely surprising, since nitration has the effect of decreasing the p K a of phenoxyl groups in free tyrosine from 10 to ~7.2

Phenformin (Cat# P7045) and SR13800 (Cat# 5096630001) were purchased from Merck (Rahway, New Jersey, USA) and dissolved in HPLC water

Robert A, Liu Y, Nguyen M, Meunier B (2015) Regulation of copper and iron homeostasis by metal chelators: a possible chemotherapy for Alzheimers disease