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Formation of the K ce side chain modification was performed by incubation of the resin with 2-bromopropionic tert -butyl ester (41.5 l, 0.250 mmol, 5.0 equiv.) and i Pr 2 Net (43.5 l, 0.250 mmol, 5.0 equiv.) in DMF (2.5 ml) at 65 C (5 h), followed by washing with DMF (3 4 ml) and CH 2 Cl 2 (3 4 ml)

Currently, several similar studies are exploring the regulatory mechanisms and clinical application prospects (Table 1)

These distinctions highlight that the mode of GSH depletion, i.e., via acute blockade of synthesis versus more gradual enhanced degradation, can differentially influence the oxidative stress response, secondary transcriptional programs, and systemic physiology

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