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Tunc-Ozdemir M, Miller G, Song L, Kim J, Sodek A, Koussevitzky S, Misra AN, Mittler R, Shintani D: Thiamin confers enhanced tolerance to oxidativestress in Arabidopsis

Catalysis is dependent on a cubane [4Fe-4S] 2+ cluster which is required to facilitate the elimination of the hydroxyl group from C 3 position of citrate (Gardner, a group in the cluster is required for coordination of the OH group on the C 3 prompting its elimination and the genesis of a cis -aconitate intermediate (Lauble and Stout, 1995)