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Cysteine residues play a valuable role by crosslinking proteins, which increases the rigidity of proteins and also functions to confer proteolytic resistance (since protein export is a costly process, minimizing its necessity is advantageous)

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However, not all reactive species are free radicals: at a pH of 7.4 0.1 they may be electroneutral molecules, able to donate electrons to free radicals, and oxidize transition metals present in cells

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