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Neither compound replaces the fundamentals

Anion exchange (positively charged stationary phase): quaternary ammonium (Q) - strong anion exchanger diethylaminoethyl (DEAE) - weak anion exchanger Cation exchange (negatively charged stationary phase): methyl sulfonate (S) - strong cation exchanger carboxymethyl (CM) - weak cation exchanger Strong exchangers should be used when the pH required for binding is very acidic or basic (assuming this pH is also appropriate for maintaining protein stability), as the functional groups remain charged over a larger pH range, [38]

Manufacturer labels often list 28 days, but real-world community use shows the peptide and the preservative both hold up well past that with clean handling and proper storage