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Doll S, Proneth B, Tyurina YY, Panzilius E, Kobayashi S, Ingold I, et al

In addition, inhibiting CytB5R3 can increase NO availability by reducing Hb from its Fe 2+ to Fe 3+ form, thereby releasing NO from its high-affinity interaction

So the study was done in 1991 and it was published at the PubMed where they were injecting two grams of IV push of glutathione and what they found out was 100% of the glutathione stayed in the plasma and nothing ever entered the blood cells