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130 The AuS binding is a well-known covalent bond where thiol groups (soft Lewis base) readily adsorb onto the reduced gold surface (soft Lewis acid) based on the Hard and Soft Acid and Base (HSAB) theory

Peptide Form: Peptides in powder form are generally more stable than those in solution

-unsaturated aldehydes (alkenals) like acrolein are highly reactive with lysine, cysteine, and histidine through a Michael-type addition as well as with serine, histidine, arginine, threonine, and lysine residues [37, 38]

However, in diabetes, oxidative stress and chronic inflammation alter IRP activity, leading to iron metabolism dysregulation, iron overload, and increased ferroptosis ( 2.3 Role of oxidative stress in diabetic cardiomyopathy In DCM, the disruption of iron homeostasis and persistent oxidative stress are key drivers of ferroptosis (62)