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When oxidant stress increases, cysteine residues on thioredoxin undergo oxidation and cross-bridging, releasing ASK1/2 from inhibition ( Figure 11 )

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NIR, near infrared

Even though the BBB is a highly selective membrane intended to protect the brain from toxins and invading pathogens, despite its semipermeable nature, the BBB is mostly impenetrable to most drugs, especially large or hydrophilic molecules, which restrict their entry into the brain and bloodstream